960化工网
A rapid and convergent synthesis of the integrastatin core†
Pamela M. Tadross,Pradeep Bugga,Brian M. Stoltz
Organic & Biomolecular Chemistry Pub Date : 05/26/2011 00:00:00 , DOI:10.1039/C1OB05725A
Abstract

The tetracyclic core of the integrastatin natural products has been prepared in a convergent and rapid manner. Our strategy relies upon a palladium(II)-catalyzed oxidative cyclization to form the central [3.3.1]-dioxabicycle of the natural product core. Overall, the core has been completed in only 4 linear steps from known compounds.

Graphical abstract: A rapid and convergent synthesis of the integrastatin core
平台客服
平台客服
平台在线客服