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Phenol-selective mass spectrometric analysis of jet fuel†
Haoxuan Zhu,Eric Janusson,Jingwei Luo,James Piers,Farhana Islam,G. Bryce McGarvey,Allen G. Oliver,Ori Granot,J. Scott McIndoe
Analyst Pub Date : 07/26/2017 00:00:00 , DOI:10.1039/C7AN00908A
Abstract

Bromobenzyl compounds react selectively with phenols via the Williamson ether synthesis. An imidazolium charge-tagged bromobenzyl compound can be used to reveal phenol impurities in jet fuel by analysis via electrospray ionization mass spectrometry. The complex matrix as revealed by Cold EI GC/MS analysis is reduced to a few simple sets of compounds in the charge-tagged ESI mass spectrum, primarily substituted phenols and thiols. Examination of jet fuels treated by different refinery methods reveals the efficacy of these approaches in removing these contaminants.

Graphical abstract: Phenol-selective mass spectrometric analysis of jet fuel
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