Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(ii) coordination†,10.1039/C6CC00707D

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(ii) coordination†

Kai Zhang,Mathew Savage,Xin Li,Yu Jiang,Masatoshi Ishida,Koki Mitsuno,Satoru Karasawa,Tatsuhisa Kato,Weihua Zhu,Sihai Yang,Hiroyuki Furuta,Yongshu Xie

Chemical Communications Pub Date : 03/10/2016 00:00:00 , DOI:10.1039/C6CC00707D

Abstract

A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(II) complexes could be systematically modulated.