4-Dibenzocyclooctynol (DIBO) as an initiator for poly(ε-caprolactone): copper-free clickable polymer and nanofiber-based scaffolds†,10.1039/C3PY00153A

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

4-Dibenzocyclooctynol (DIBO) as an initiator for poly(ε-caprolactone): copper-free clickable polymer and nanofiber-based scaffolds†

Jukuan Zheng,Sibai Xie,Fei Lin,Geng Hua,Tianyi Yu,Darrell H. Reneker

Polymer Chemistry Pub Date : 02/08/2013 00:00:00 , DOI:10.1039/C3PY00153A

Abstract

Utilization of 4-dibenzocyclooctynol (DIBO) as an initiator for the ring-opening polymerization of ε-caprolactone yields well-defined, high molecular weight poly(ε-caprolactone) end functionalized with DIBO (DIBO–PCL). Nanofibers bearing reactive DIBO groups were generated via electrospinning and functionalized post-fabrication with azide-tethered molecules.