New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands†,10.1039/C5DT04088D

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands†

Mio Sekino,Hideki Furutachi,Kyosuke Tasaki,Takanao Ishikawa,Shigeki Mori,Shuhei Fujinami,Shigehisa Akine,Yoko Sakata,Takashi Nomura,Takashi Ogura,Teizo Kitagawa,Masatatsu Suzuki

Dalton Transactions Pub Date : 11/23/2015 00:00:00 , DOI:10.1039/C5DT04088D

Abstract

(μ-1,2-Peroxo)diiron(III) complexes (2-R) with dinucleating ligands (R-L) generated from the reaction of bis(μ-hydroxo)diiron(II) complexes [Fe₂(R-L)(OH)₂]²⁺ (1-R) with dioxygen in acetone at −20 °C provide a diiron-centred electrophilic oxidant, presumably diiron(IV)-oxo species, which is involved in aromatic ligand hydroxylation.