In this work, nickel–cobalt alloy nanoparticles were electrodeposited on/in an electrochemically reduced nitrogen-doped graphene oxide (ErN-GO)/carbon-ceramic electrode (CCE) and the resulting nanocomposite (NiCo/ErN-GO/CCE) was evaluated as a low cost electrocatalyst for methanol and ethanol electrooxidation. Field-emission scanning electron microscopy coupled with energy dispersive X-ray spectroscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy were used for the physical characterization of the electrocatalyst. To study the electrochemical behavior and electrocatalytic activity of the prepared electrocatalyst towards the oxidation of methanol and ethanol in alkaline media, cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy were utilized. Electrochemical investigation of the introduced electrocatalysts (NiCo alloy and Ni nanoparticles alone electrodeposited on/in different substrates) indicated that NiCo/ErN-GO/CCE has highest activity and stability towards methanol (J_p = 88.04 mA cm⁻²) and ethanol (J_p = 64.23 mA cm⁻²) electrooxidation, which highlights its potential use as an anodic material in direct alcohol fuel cells.