Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(i)†
Mark R. Crimmin,Michael J. Butler,Andrew J. P. White
Chemical Communications Pub Date : 09/14/2015 00:00:00 , DOI:10.1039/C5CC07140B
Abstract
Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre.