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Novel cerium(iv) heteropolyoxotungstate containing two types of lacunary Keggin anions†
Filipa L. Sousa,Ana M. V. Cavaleiro,Jacek Klinowski,Helena I. S. Nogueira
Chemical Communications Pub Date : 10/08/2004 00:00:00 , DOI:10.1039/B409034A
Abstract

A novel V-shaped polyoxotungstate is formed when CeIV metal centres bridge monolacunary [PW11O39]7− anions to an unusual 1,4-bilacunary [PW10O38]11− anion which appears with an unprecedented bridging structural motif.

Graphical abstract: Novel cerium(iv) heteropolyoxotungstate containing two types of lacunary Keggin anions
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