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Palladium-catalyzed unsymmetrical aryl couplings in sequence leading to o-teraryls: dramatic olefin effect on selectivity†
Elena Motti,Nicola Della Ca’,Sara Deledda,Emanuela Fava,Francesca Panciroli,Marta Catellani
Chemical Communications Pub Date : 05/11/2010 00:00:00 , DOI:10.1039/C000526F
Abstract

Selectively substituted o-teraryls are obtained by palladium/norbornene-catalyzed reaction of aryl iodides, aryl bromides and aryl boronic acids in ordered sequence; high selectivity is attained thanks to the addition of diethyl maleate acting as palladium ligand.

Graphical abstract: Palladium-catalyzed unsymmetrical aryl couplings in sequence leading to o-teraryls: dramatic olefin effect on selectivity
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