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Quantitative XRD characterisation and gas-phase photocatalytic activity testing for visible-light (indoor applications) of KRONOClean 7000®†
D. M. Tobaldi,M. P. Seabra,G. Otero-Irurueta,Y. R. de Miguel,R. J. Ball,M. K. Singh,R. C. Pullar,J. A. Labrincha
RSC Advances Pub Date : 11/26/2015 00:00:00 , DOI:10.1039/C5RA22816F
Abstract

Carbon-modified commercial anatase (KRONOClean 7000®) was quantitatively characterised with XRD for the first time – full phase composition (both crystalline and amorphous content) and microstructure. The material was found to be bimodal anatase, mostly ∼4 nm diameter, but with a small amount of a larger fraction between ∼12 and 15 nm. Absorption in the visible range was confirmed by UV-Vis analysis, whilst XPS showed that an aromatic carbon compound is at the origin of that absorption. Also, the photocatalytic activity of this commercial nano-TiO2 was assessed, monitoring the abatement of NOx using a white LED lamp, irradiating exclusively in the visible region. Experiments simulated an indoor environment, highlighting the potential of this nano-TiO2 for adoption as a standard for visible-light photocatalytic activity, i.e. applications for innovative interior eco-building materials.

Graphical abstract: Quantitative XRD characterisation and gas-phase photocatalytic activity testing for visible-light (indoor applications) of KRONOClean 7000®
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