960化工网
One-pot solvothermal synthesis of bimetallic yolk–shell Ni@PtNi nanocrystals supported on reduced graphene oxide and their excellent catalytic properties for p-nitrophenol reduction†
Li-Ping Mei,Rui Wang,Pei Song,Jiu-Ju Feng,Zhi-Gang Wang,Jian-Rong Chen,Ai-Jun Wang
New Journal of Chemistry Pub Date : 01/07/2016 00:00:00 , DOI:10.1039/C5NJ02923F
Abstract

Well-defined bimetallic yolk–shell nanostructures of Ni@PtNi nanocrystals with porous shells were uniformly deposited on reduced graphene oxide (Ni@PtNi NCs-rGO) under hydrothermal conditions. The physical characterization was systematically investigated by transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The as-fabricated products exhibited improved catalytic performance toward the reduction of p-nitrophenol in comparison with commercial Pt/C (50 wt%), monometallic Pt nanoparticles/rGO and Ni nanoparticles/rGO catalysts.

Graphical abstract: One-pot solvothermal synthesis of bimetallic yolk–shell Ni@PtNi nanocrystals supported on reduced graphene oxide and their excellent catalytic properties for p-nitrophenol reduction
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