One-pot synthesis of benzo[c]carbazoles by photochemical annulation of 2-chloroindole-3-carbaldehydes†
Cailin Wang,Wei Zhang,Shenci Lu,Jingfei Wu,Zongjun Shi
Chemical Communications Pub Date : 09/12/2008 00:00:00 , DOI:10.1039/B808854C
Abstract
A novel and efficient procedure for the synthesis of benzo[c]carbazoles has been achieved in moderate to high yields by the one-pot photochemical annulations of 2-chloroindole-3-carbaldehydes by styrenesvia photodechlorination-initiated coupling of 2-chloroindole-3-carbaldehydes with styrenes, electrocyclic reactions and deformylative aromatization in the presence of pyridine.