Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations†,10.1039/D0NJ00343C

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Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations†

Andressa Lunardi,Camila Nunes Cechin,Ernesto Schulz Lang,Roberta Cargnelutti,Nahum Ramirez Pineda,Paulo Cesar Piquini,Robert Alan Burrow,Sailer Santos dos Santos,Tanize Bortolotto,Bárbara Tirloni

New Journal of Chemistry Pub Date : 03/26/2020 00:00:00 , DOI:10.1039/D0NJ00343C

Abstract

Novel tetranuclear zinc compounds, [Zn₄(μ-SeO₃)₂(μ₄-SeO₃)₂(bipy)₄]·11H₂O (1) and [Zn₄(μ-SeO₃)₂(μ₄-SeO₃)₂(phen)₄]·9H₂O (2), which are the first examples of organically templated zinc selenite compounds containing closed-frameworks, have been synthesized via solvothermal processes. The compounds were characterized by spectroscopy, crystallographic methods and DFT calculations.