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Solution concentration controlled self-assembling structure with host–guest recognition at the liquid–solid interface†
Junyong Zhang,Ke Deng,Jingli Xie,Wubiao Duan,Qingdao Zeng
Physical Chemistry Chemical Physics Pub Date : 08/24/2015 00:00:00 , DOI:10.1039/C5CP04065E
Abstract

In the present investigation, we reported the fabrication of a chicken-wire porous 2D network formed by triphenylene-2,6,10-tricarboxylic acid (H3TTCA) at the liquid–solid interface. When coronene (COR) molecules were added into the system, the H3TTCA honey-comb network was broken and the reconstructed structures of the H3TTCA/COR host–guest systems were subsequently formed. Scanning tunneling microscopic (STM) measurements and density function theory (DFT) calculations were utilized to reveal the structural variety in the co-assembly of H3TTCA/COR controlled by the solution concentration at 1-heptanoic acid/HOPG interface.

Graphical abstract: Solution concentration controlled self-assembling structure with host–guest recognition at the liquid–solid interface
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