Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells†,10.1039/C6DT02881K

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells†

I. R. Knyazeva,R. A. Safiullin,V. I. Matveeva,V. V. Khrizanforova,T. I. Ismaev,A. R. Burilov,Yu. H. Budnikova,O. G. Sinyashin

Dalton Transactions Pub Date : 09/30/2016 00:00:00 , DOI:10.1039/C6DT02881K

Abstract

The catalytic activity of the nickel complexes of thiophosphorylated calix[4]resorcinols for oxygen reduction in a polymer electrolyte membrane fuel cell (PEMFC) has been studied. The conformation of the macrocyclic ligand determines the morphology and catalytic properties of the resulting organometallic species.