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Oscillations in the primary charge separation in bacterial photosynthesis
Physical Chemistry Chemical Physics Pub Date : 04/30/2002 00:00:00 , DOI:10.1039/B102700J
Abstract

This paper examines the temporal evolution of an electron in a photosynthetic reaction center. A model based on self-consistent quantum-mechanical equations is suggested to describe the picosecond transfer of an electron from an excited primary donor, the excited bacteriochlorophyll dimer (P*), to bacteriopheophytin (H). This transfer is shown to have an oscillation behavior. The results obtained offer an explanation for oscillations in the emission kinetics of the primary donor excited state.

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