Oxidation of aromatic alkenes and alkynes catalyzed by a hexa-acetonitrile iron(ii) ionic complex [Fe(CH3CN)6][BF4]2†,10.1039/C8NJ02226G

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Oxidation of aromatic alkenes and alkynes catalyzed by a hexa-acetonitrile iron(ii) ionic complex [Fe(CH3CN)6][BF4]2†

Chew Pheng Yap,Jing Kuang Ng,Sherzod Madrahimov,Ashfaq A. Bengali,Tsz Sian Chwee,Wai Yip Fan

New Journal of Chemistry Pub Date : 05/28/2018 00:00:00 , DOI:10.1039/C8NJ02226G

Abstract

Oxidative cleavage of aromatic alkenes and oxidation of alkynes have been catalyzed by a simple Fe(II) complex [Fe(CH₃CN)₆][BF₄]₂ using H₂O₂ as an oxidant at room temperature. A free radical mechanism has been proposed involving the peroxy (OOH) radical to account for our experimental findings.