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Stereocontrolled synthesis of lepadiformine A
Barry Lygo,Eirene H. M. Kirton,Christopher Lumley
Organic & Biomolecular Chemistry Pub Date : 07/02/2008 00:00:00 , DOI:10.1039/B805951A
Abstract

In this paper we present results of a study into whether the tricyclic core of the lepadiformines A–C can be accessed via intramolecular hetero-Diels–Alder cycloaddition. We are able to demonstrate that such a process is possible and that the reaction proceeds in an endo-selective fashion, providing the correct relative stereochemistry for this family of natural products. By employing this approach we have been able to develop a short (7 step) synthesis of (±)-lepadiformine A, starting from commercially-available trans-2-nonenal.

Graphical abstract: Stereocontrolled synthesis of lepadiformine A
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