Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes†
Feng Zhao,Bin Li,Huawen Huang
RSC Advances Pub Date : 01/26/2016 00:00:00 , DOI:10.1039/C5RA26588F
Abstract

A palladium-catalyzed construction for N-arylsulfonamide from nitroarenes and arylsulfonyl hydrazides is developed. In this protocol, abundant and stable nitroarenes serve as the nitrogen sources by in situ reduction reaction of hydrogen released from arylsulfonyl hydrazides. No external oxidants or reductants are needed for this kind of transformation.

Graphical abstract: Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes