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Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural†
Songyan Jia,Xinjun He,Jiao Ma,Zhanwei Xu,Kangjun Wang,Z. Conrad Zhang
RSC Advances Pub Date : 09/19/2018 00:00:00 , DOI:10.1039/C8RA07027J
Abstract

Phosphorus pentoxide (P2O5)/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither P2O5 nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85% selectivity could be achieved within 30 min at 80 °C.

Graphical abstract: Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural
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