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Phosphabarrelene–rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes†
Bernhard Breit,Evelyn Fuchs
Chemical Communications Pub Date : 02/13/2004 00:00:00 , DOI:10.1039/B315709A
Abstract

A new class of phosphabarrelene–rhodium catalysts is described which allows for the first time hydroformylation of internal alkenes with very high activity and which proceeds essentially free of alkene isomerization.

Graphical abstract: Phosphabarrelene–rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes
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