Solvent dependent reductive defluorination of aliphatic C–F bonds employing Sm(HMDS)2†,10.1039/C3CC37828D

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Solvent dependent reductive defluorination of aliphatic C–F bonds employing Sm(HMDS)2†

Mario Janjetovic,Annika M. Träff,Tobias Ankner,Jenny Wettergren,Göran Hilmersson

Chemical Communications Pub Date : 01/10/2013 00:00:00 , DOI:10.1039/C3CC37828D

Abstract

Sm(HMDS)₂ in n-hexane mediates fast cleavage of primary, secondary and tertiary alkyl fluorides in good to excellent yields. In n-hexane Sm(HMDS)₂ exhibits uniquely enhanced reductive ability towards the C–F bond compared to when using THF as solvent.