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Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions†
Kazuya Imamura,Hiroko Kato,Yuichiro Wada,Kazuhiro Makabe,Ayumu Onda,Atsuhiro Tanaka,Hiroshi Kominami,Katsutoshi Nagaoka
Chemical Communications Pub Date : 05/17/2018 00:00:00 , DOI:10.1039/C8CC03362E
Abstract

In the presence of a palladium-loaded TiO2 photocatalyst, the cleavage of benzyl phenyl ether in low-molecular-weight alcohol solvents under de-aerated conditions afforded toluene and phenol simultaneously in a 1 : 1 molar ratio.

Graphical abstract: Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions
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