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p-tert-Butylcalix[8]arene: A support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties†
Ruaraidh D. McIntosh,Stephanie M. Taylor,Sergio Sanz,Christine M. Beavers,Simon J. Teat,Euan K. Brechin,Scott J. Dalgarno
Dalton Transactions Pub Date : 09/28/2011 00:00:00 , DOI:10.1039/C1DT10821B
Abstract

A series of new sodium and mixed sodium/manganese clusters have been formed using p-tert-butylcalix[8]arene as a support. In all cases the calixarene adopts the pleated-loop conformation, and the resulting complexes show interesting self-assembly properties depending on the ligated solvent molecules around individual cluster cores.

Graphical abstract: p-tert-Butylcalix[8]arene: A support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties
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