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Self-assembly of a molecular crown as a structural analogue of calix[4]arene to modify Keggin anions†
Aixiang Tian,Xiaoling Lin,Jun Ying,Juwen Zhang,Hongyan Lin,Guocheng Liu,Dan Zhao,Na Li,Xiuli Wang
Dalton Transactions Pub Date : 05/09/2013 00:00:00 , DOI:10.1039/C3DT50800E
Abstract

Four AgI ions are linked by four 5-phenyl-1H-tetrazole (Hptz) units to form a molecular crown [Ag4(ptz)4] as a structural analogue of calix[4]arene, which are further supported by Keggin anions to build a 2D layer containing two kinds of cycles, [Ag8(ptz)4(HPWV2WVI10O40)]·2H2O (1).

Graphical abstract: Self-assembly of a molecular crown as a structural analogue of calix[4]arene to modify Keggin anions
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