Pyrite (FeS₂) nanorod arrays were produced on a fluorine doped tin oxide substrate by sulfurizing FeO(OH) nanorods, and then tested as the counter electrode (CE) for dye-sensitized solar cells (DSSCs). FeS₂ nanorods show better catalytic properties than the FeS₂ film and the Pt film due to their active facets, which helps to achieve a high short-circuit photocurrent density (J_sc) of DSSCs. On the other hand, FeS₂ nanorods have lower interface resistance than FeS₂ thin films, which contributes to a higher fill factor (FF) of DSSCs. As a result, the solar cell with a CE of FeS₂ nanorods exhibits an excellent power conversion efficiency, which is comparable to that of traditional DSSCs with a Pt CE.