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Stabilisation of a triply-bridging cyclopentadienylligand in a tetrapalladium cluster†‡
Kirill Yu. Monakhov,Christophe Gourlaouen,Pierre Braunstein
Chemical Communications Pub Date : 06/12/2012 00:00:00 , DOI:10.1039/C2CC32886K
Abstract

An unusual triply-bridging cyclopentadienyl (C5H5 = Cp) ligand has been characterised in the tetranuclear palladium cluster [Pd3II(μ-OAc)43-Cp)Pd05-Cp)] (1). It is coordinated in the μ3122 mode to a [Pd3]4+ triangular subunit of the mixed-valence cluster 1.

Graphical abstract: Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster
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