An unusual triply-bridging cyclopentadienyl (C5H5 = Cp) ligand has been characterised in the tetranuclear palladium cluster [Pd3II(μ-OAc)4(μ3-Cp)Pd0(η5-Cp)] (1). It is coordinated in the μ3-η1:η2:η2 mode to a [Pd3]4+ triangular subunit of the mixed-valence cluster 1.