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Rapid (<3 min) microwave synthesis of block copolymer templated ordered mesoporous metal oxide and carbonate films using nitrate–citric acid systems†
Yuanzhong Zhang,Sarang M. Bhaway,Yi Wang,Kevin A. Cavicchi,Matthew L. Becker,Bryan D. Vogt
Chemical Communications Pub Date : 02/16/2015 00:00:00 , DOI:10.1039/C4CC09808K
Abstract

Rapid chemical transformation from micelle templated precursors (metal nitrate and citric acid) to ordered mesoporous metal carbonates and oxides is demonstrated using microwave heating for cobalt, copper, manganese and zinc. Without aging requirements, <3 min of microwave processing yields highly ordered mesoporous films.

Graphical abstract: Rapid (<3 min) microwave synthesis of block copolymer templated ordered mesoporous metal oxide and carbonate films using nitrate–citric acid systems
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