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Physical gelation of polar aprotic solvents induced by hydrogen bonding modulation of polymeric molecules†
Duyoun Ka,Myungeun Seo,Hyungsam Choi,Eun Hee Kim,Sang Youl Kim
Chemical Communications Pub Date : 07/01/2010 00:00:00 , DOI:10.1039/C0CC00994F
Abstract

Poly(aryl ether amide) containing o-nitroanilide forms a physical gel in polar aprotic solvents by solvent-induced change of hydrogen bonding modes, in which hydrogen bonding acceptor solvent molecules break intramolecular hydrogen bonding of o-nitroanilide and induce intermolecular hydrogen bonding.

Graphical abstract: Physical gelation of polar aprotic solvents induced by hydrogen bonding modulation of polymeric molecules
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