Synthesis of cyclic carbonates from epoxides and carbon dioxide catalyzed by an easy-to-handle ionic iron(iii) complex†,10.1039/C3DT32961E

批量搜索

批量搜索

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Synthesis of cyclic carbonates from epoxides and carbon dioxide catalyzed by an easy-to-handle ionic iron(iii) complex†

M. A. Fuchs,T. A. Zevaco,E. Ember,O. Walter,I. Held,E. Dinjus,M. Döring

Dalton Transactions Pub Date : 01/29/2013 00:00:00 , DOI:10.1039/C3DT32961E

Abstract

We report the successful utilization of monometallic, ionic iron(II)– and iron(III)–N₂O₂–ligand-systems as highly active homogeneous catalysts for the conversion of CO₂ with different epoxides to cyclic carbonates. The catalytic tests were performed using propylene oxide (PO) and a range of nine substituted epoxides. Terminal monosubstituted oxides react quantitatively.