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Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides†
L. Rassaei,W. Olthuis,G. W. Nelson,J. S. Foord,P. Holdway,M. Carta,R. Malpass-Evans,N. B. McKeown,S. C. Tsang,R. Castaing,T. R. Forder,M. D. Jones,D. He,F. Marken
RSC Advances Pub Date : 08/24/2015 00:00:00 , DOI:10.1039/C5RA15131G
Abstract

The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) – associated with a high thermolysis threshold – combined with the possibility to fill intrinsic micropores allows the direct “one-step” templated conversion of metal nitrates into nano-structured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)3 to Pr6O11.

Graphical abstract: Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides
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