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Preservation of the cluster core upon formation of Ti3O(OPri)8(benzoate)2 from Ti3O(OR)10
Ivan Mijatovic,Guido Kickelbick,Michael Puchberger,Ulrich Schubert
New Journal of Chemistry Pub Date : 11/14/2002 00:00:00 , DOI:10.1039/B208255A
Abstract

The cluster Ti3O(OPri)8(benzoate)2 is obtained upon reaction of Ti3O(OPri)10 or Ti3O(OPri)9(OMe) with benzoic acid. The remarkable feature of this substitution reaction is that the cluster structure is approximately preserved. Ti3O(OPri)8(benzoate)2 undergoes a dynamic exchange processes of the propoxy groups in solution.

Graphical abstract: Preservation of the cluster core upon formation of Ti3O(OPri)8(benzoate)2 from Ti3O(OR)10
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