Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability†,10.1039/C7CC05068B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability†

J. Hynek,S. Ondrušová,D. Bůžek,P. Kovář,J. Rathouský,J. Demel

Chemical Communications Pub Date : 07/06/2017 00:00:00 , DOI:10.1039/C7CC05068B

Abstract

A zirconium metal–organic framework (MOF) PCN-222 was postsynthetically modified with diphenylphosphinic acid, resulting in an increased stability when activated from water and 4 times higher photosensitizing properties for singlet oxygen production. The phosphinic acid did not compromise the crystallinity of the MOF but made strong bonds with the zirconia secondary building units.