Reduction of CO2 to free CO by a Pd(i)–Pd(i) dimer†
Chandra Mouli Palit,Daniel J. Graham,Chun-Hsing Chen,Bruce M. Foxman,Oleg V. Ozerov
Chemical Communications Pub Date : 07/07/2014 00:00:00 , DOI:10.1039/C4CC02438A
Abstract

Reaction of CO2 with a Pd(I)–Pd(I) dimer supported by amido/bis(phosphine) pincer PNP ligands produces free CO in the presence of Me3SiCl and Me3SiOTf.

Graphical abstract: Reduction of CO2 to free CO by a Pd(i)–Pd(i) dimer