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Terminal alkyne substituted O6-benzylguanine for versatile and effective syntheses of fluorescent labels to genetically encoded SNAP-tags†
Xinbo Song,Chao Wang,Zhuo Han,Yongping Xu,Yi Xiao
RSC Advances Pub Date : 02/26/2015 00:00:00 , DOI:10.1039/C4RA17072E
Abstract

We have developed a terminal alkyne substituted O6-benzylguanine, named PYBG, as a versatile precursor to be facilely conjugated with various fluorescent dyes through ‘Click chemistry’ and Sonogashira coupling reactions. These fluorescent PYBG derivatives specifically and efficiently label the target genetically encoded SNAP-tags in live cells.

Graphical abstract: Terminal alkyne substituted O6-benzylguanine for versatile and effective syntheses of fluorescent labels to genetically encoded SNAP-tags
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