Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P–C cross-coupling†
Christian Korff,Günter Helmchen
Chemical Communications Pub Date : 02/03/2004 00:00:00 , DOI:10.1039/B315009G
Abstract
Enantioselective C–P cross-coupling of diarylphosphines and ortho-substituted aryl iodides has been achieved with >90%ee, using an in situcatalyst prepared from Et,Et-FerroTANE, Pd2(dba)3×CHCl3 and LiBr.
