It is a great challenge to tune the porosity of porous materials. As most porous organic cages are soluble, solution processability can be a possible way to regulate the porosity of such materials. Herein, a triptycene-based cage (TC) is demonstrated to be stable in acid, base or boiling water. Meanwhile, its porosity can be tuned by adjusting the solution-state assembly processes. TC molecules crystallized slowly from solution exhibit nearly no porosity to nitrogen (off-state). While, after rapid precipitating from methanol/dichloromethane solution, the obtained TC (TC-rp) is in a porous state and exhibit a high BET surface area of 653 m2 g−1 (on-state).
