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A triple-triangle cluster derived from a simple tridentate ligand†
Takuya Shiga,Natsumi Okawa
Dalton Transactions Pub Date : 11/05/2019 00:00:00 , DOI:10.1039/C9DT03232K
Abstract

The heptanuclear ferric cluster, [FeIII7(O)6(HL)5(H2L)(H2O)8](BF4)4 (H2L = 2,6-bis(1,5-diphenyl-1H-pyrazol-3-yl)pyridine), was synthesized by the reaction of the planar tridentate ligand H2L with iron(II) tetrafluoroborate hexahydrate. The cluster has a corner-shared triple-triangle core structure connected by three μ-O atoms, and it has a spin-frustrated ferrimagnetic spin ground state of S = 19/2.

Graphical abstract: A triple-triangle cluster derived from a simple tridentate ligand
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