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Probing the existence of uranyl trisulfate structures in the AMEX solvent extraction process†
Tamir Sukhbaatar,Magali Duvail,Thomas Dumas,Sandrine Dourdain,Guilhem Arrachart,Pier Lorenzo Solari,Philippe Guilbaud,Stéphane Pellet-Rostaing
Chemical Communications Pub Date : 06/03/2019 00:00:00 , DOI:10.1039/C9CC02651G
Abstract

Knowledge of the complex microstructure in solvent extraction phases is mandatory for a full comprehension of ionic separation. Coupling EXAFS with MD simulations for uranyl extraction in sulfuric media with tertiary amine extractants enabled unravelling of the unprecedented uranyl tri-sulfate structure.

Graphical abstract: Probing the existence of uranyl trisulfate structures in the AMEX solvent extraction process
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