Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry†
Thomas R. Hayes,Benjamin B. Kasten,Charles L. Barnes,Paul D. Benny
Dalton Transactions Pub Date : 03/27/2014 00:00:00 , DOI:10.1039/C4DT00684D
Abstract
A versatile strategy to prepare fac-[MI(CO)3]+ and cis-[MI(CO)2]+ (M = Re, 99mTc) complexes was developed using Huisgen click chemistry and monodentate phosphine ligands to readily incorporate biomolecules and tailor the chemical properties.