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A supramolecular nematic phase in sulfonated polyaramides
Sebastien Viale,Adam S. Best,Eduardo Mendes,Wolter F. Jager,Stephen J. Picken
Chemical Communications Pub Date : 06/09/2004 00:00:00 , DOI:10.1039/B404809C
Abstract

A water-soluble polyaramide “sulfo-invert-PPTA” surprisingly, already at a molecular weight of 10,000 g mol−1, exhibits a nematic liquid crystalline phase in water at very low polymer concentrations, around 1–2wt%, indicating that supramolecular assemblies of molecules are the building blocks of the nematic phase.

Graphical abstract: A supramolecular nematic phase in sulfonated polyaramides
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