Quantitative formation of [4]pseudorotaxanes from two rods and two bis-macrocycles incorporating porphyrinic plates between the rings†‡
Jean-Paul Collin,Fabien Durola,Julien Frey,Valérie Heitz,Jean-Pierre Sauvage,Christian Tock,Yann Trolez
Chemical Communications Pub Date : 02/26/2009 00:00:00 , DOI:10.1039/B901482A
Abstract

[4]Pseudorotaxanes consisting of two very large coordinating bis-macrocycles and rigid rods incorporating two side-by-side chelates have been obtained quantitatively utilising the gathering and threading effect of copper(I); the assemblies obtained are several nanometres long and they contain two face-to-face zinc porphyrins which will be used to complex various organic substrates.

Graphical abstract: Quantitative formation of [4]pseudorotaxanes from two rods and two bis-macrocycles incorporating porphyrinic plates between the rings