Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate†,10.1039/C3PY01128C

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate†

Daniel P. Sanders,Daniel J. Coady,Manabu Yasumoto,Masaki Fujiwara,Haritz Sardon,James L. Hedrick

Polymer Chemistry Pub Date : 09/23/2013 00:00:00 , DOI:10.1039/C3PY01128C

Abstract

Functionalized cyclic carbonate monomers were synthesized via a two step route featuring a novel cyclic carbonate intermediate possessing a pendent activated pentafluorophenyl carbonate group (MTC-PFPC). The pentafluorophenyl carbonate of MTC-PFPC was selectively substituted with suitable nucleophiles such as alcohols, amines and thiols generating functionalized cyclic carbonates in moderate to high yield.