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The origin of open circuit voltage of porphyrin-sensitised TiO2 solar cells
Attila J. Mozer,Pawel Wagner,David L. Officer,Gordon G. Wallace,Wayne M. Campbell,Masanori Miyashita,Kenji Sunahara,Shogo Mori
Chemical Communications Pub Date : 08/29/2008 00:00:00 , DOI:10.1039/B805027A
Abstract

Electron lifetime and diffusion coefficient measurements in highly efficient porphyrin-sensitised TiO2 solar cells showed reduced electron lifetime, and consequently, lower photo-induced electron density under illumination compared to commonly used ruthenium dye (N719)-sensitised solar cells, which is proposed to be the origin of the generally lower open circuit voltage.

Graphical abstract: The origin of open circuit voltage of porphyrin-sensitised TiO2 solar cells
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