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Supramolecular polymer fabricated by click polymerization from supramonomer†
Liulin Yang,Xiaoguang Liu,Xinxin Tan,Hui Yang,Zhiqiang Wang,Xi Zhang
Polymer Chemistry Pub Date : 09/10/2013 00:00:00 , DOI:10.1039/C3PY01161E
Abstract

In contrast with macromonomer in traditional polymer science, supramonomer refers to a monomer that is fabricated by noncovalent interactions, but is able to polymerize using conventional methods of polymerization. This communication describes the fabrication of a supramonomer based on supramolecular complexation between cucurbit[8]uril and the tripeptide Phe-Gly-Gly derivative. The supramolecular polymer is obtained by click polymerization of the supramonomer. It is expected that this line of research will provide a new method for fabricating supramolecular polymers.

Graphical abstract: Supramolecular polymer fabricated by click polymerization from supramonomer
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