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Surface binding vs. sequestration; the uptake of benzohydroxamic acid at iron(iii) oxide surfaces†
Iria M. Rio-Echevarria,Fraser J. White,Euan K. Brechin,Peter A. Tasker,Steven G. Harris
Chemical Communications Pub Date : 08/06/2008 00:00:00 , DOI:10.1039/B808805E
Abstract

Benzohydroxamic acid is shown to be an unexpectedly good ligand for iron(III) oxides, favouring surface attachment to the formation of trisbenzohydroxamato complexes, which are known to have very high thermodynamic stability in solution.

Graphical abstract: Surface binding vs. sequestration; the uptake of benzohydroxamic acid at iron(iii) oxide surfaces
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