960化工网
Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih†
D. S. Krylov,F. Liu,S. M. Avdoshenko,L. Spree,B. Weise,A. Waske,A. U. B. Wolter,B. Büchner,A. A. Popov
Chemical Communications Pub Date : 06/16/2017 00:00:00 , DOI:10.1039/C7CC03580B
Abstract

The Dy-Sc nitride clusterfullerene Dy2ScN@C80-Ih exhibits slow relaxation of magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth-excited Kramers doublet with the energy of 1735 ± 21 K, which is the highest barrier ever reported for dinuclear lanthanide single molecule magnets.

Graphical abstract: Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih
平台客服
平台客服
平台在线客服