Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides†
Naoki Hayashi,Kazunao Kusano,Shingo Sekizawa,Ikuya Shibata,Makoto Yasuda,Akio Baba
Chemical Communications Pub Date : 09/14/2007 00:00:00 , DOI:10.1039/B712998J
Abstract
Regio- and stereoselective hydrostannation of allenes by using di-n-butyliodotin hydride (Bu2SnIH) was accomplished to give α,β-disubstituted vinyltins, which induced the synthesis of multi-substituted alkenes in a one-pot procedure.