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Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks†
Tomohiro Higashino,Atsushi Kumagai
Chemical Communications Pub Date : 03/17/2017 00:00:00 , DOI:10.1039/C7CC01273J
Abstract

We synthesized for the first time octaphyrins with a dithieno[3,4-b:3′,4′-d]thiophene core as thiophene-fused dithiaoctaphyrins with a cross-conjugated structure. The octaphyrins revealed cross-conjugated and macrocyclic 36π-electron networks.

Graphical abstract: Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks
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