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Remarkable enhancement of reactivity of carbonyl compounds for polymerizations with non-activated aromatic hydrocarbons
Mikhail Zolotukhin,Serguei Fomine,Roberto Salcedo,Leonard Khalilov
Chemical Communications Pub Date : 03/25/2004 00:00:00 , DOI:10.1039/B317108F
Abstract

Reaction of carbonyl compounds bearing electron-withdrawing substituents with non-activated aromatic hydrocarbons proceeds selectively in trifluoromethanesulfonic acid (TFSA) at room temperature to give linear, high-molecular-weight polymers.

Graphical abstract: Remarkable enhancement of reactivity of carbonyl compounds for polymerizations with non-activated aromatic hydrocarbons
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